A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 29980687.
- Also identified by DOI 10.1038/s41467-018-05141-4 and PMC identifier 6035257.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Metal-organic frameworks (MOFs) have so far been highlighted for their potential roles in catalysis, gas storage and separation. However, the realization of high electrical conductivity (>10<sup>-3</sup> S cm<sup>-1</sup>) and magnetic ordering in MOFs will afford them new functions for spintronics, which remains relatively unexplored. Here, we demonstrate the synthesis of a two-dimensional MOF by solvothermal methods using perthiolated coronene as a ligand and planar iron-bis(dithiolene) as linkages enabling a full π-d conjugation. This 2D MOF exhibits a high electrical conductivity of ~10 S cm<sup>-1</sup> at 300 K, which decreases upon cooling, suggesting a typical semiconductor nature. Magnetization and <sup>57</sup>Fe Mössbauer experiments reveal the evolution of ferromagnetism within nanoscale magnetic clusters below 20 K, thus evidencing exchange interactions between the intermediate spin S = 3/2 iron(III) centers via the delocalized π electrons. Our results illustrate that conjugated 2D MOFs have potential as ferromagnetic semiconductors for application in spintronics.