Geometrical percolation threshold of congruent cuboidlike particles in overlapping particle systems.

Abstract

With the advances in artificial particle synthesis, it is possible to create particles with unique shapes. Particle shape becomes a feasible parameter for tuning the percolation behavior. How to accurately predict the percolation threshold by particle characteristics for arbitrary particles has aroused great interest. Towards this end, a versatile family of cuboidlike particles and a numerical contact detection algorithm for these particles are presented here. Then, combining with percolation theory, the continuum percolation of randomly distributed overlapping cuboidlike particles is studied. The global percolation threshold ϕ_{c} of overlapping particles with broad ranges of the shape parameter m in [1.0,+∞) and aspect ratio a/b in [0.1, 10.0] is computed via a finite-size scaling technique. Using the generalized excluded-volume approximation, an analytical formula is proposed to quantify the dependence of ϕ_{c} on the parameters m and a/b, and its reliability is verified. The results reveal that the percolation threshold ϕ_{c} of overlapping cuboidlike particles is heavily dependent on the shapes of particles, and much more sensitive to a/b than m. As the cuboidlike particles become spherical (i.e., m=1.0 and a/b=1.0), the maximum threshold ϕ_{c,max} can be obtained.