Nanoliter deposition on star-shaped hydrophilic-superhydrophobic patterned surfaces.

Abstract

Nanoliter sized droplet deposition has gained increasing importance in many biomedical, chemical, and microfluidic applications and in materials synthesis. In this paper, we report a simple method for rapid and high-throughput deposition of nanoliter-sized droplets by dragging a larger droplet on star-shaped hydrophilic-superhydrophobic patterned surfaces. Dragging a droplet on the patterned surface causes water to adhere to hydrophilic patterns. As the larger mother droplet detaches from a star-shaped pattern, a small daughter droplet is deposited on the pattern. Star-shaped hydrophilic patterns with a distinct number of spikes are fabricated and investigated. Systematic tests are carried out to study the influence of different process parameters including the volume of a mother droplet, the dragging velocity, the number of spikes and the dragging directions to the deposition process. The results indicate that creating microarrays by dragging large droplets on patterned hydrophilic-superhydrophobic surfaces yield a reliable, cost-efficient, high-accuracy and easily scalable deposition. The volume of the daughter droplet grows with the velocity of the mother droplet and the number of spikes in a pattern, and decreases with the volume of the mother droplet.