Dendritic defect-rich palladium-copper-cobalt nanoalloys as robust multifunctional non-platinum electrocatalysts for fuel cells.

Abstract

Recently, the development of high-performance non-platinum electrocatalysts for fuel cell applications has been gaining attention. Palladium-based nanoalloys are considered as promising candidates to substitute platinum catalysts for cathodic and anodic reactions in fuel cells. Here, we develop a facile route to synthesize dendritic palladium-copper-cobalt trimetallic nanoalloys as robust multifunctional electrocatalysts for oxygen reduction and formic acid oxidation. To the best of our knowledge, the mass activities of the dendritic Pd₅₉Cu₃₀Co₁₁ nanoalloy toward oxygen reduction and formic acid oxidation are higher than those previously reported for non-platinum metal nanocatalysts. The Pd₅₉Cu₃₀Co₁₁ nanoalloys also exhibit superior durability for oxygen reduction and formic acid oxidation as well as good antimethanol/ethanol interference ability compared to a commercial platinum/carbon catalyst. The high performance of the dendritic Pd₅₉Cu₃₀Co₁₁ nanoalloys is attributed to a combination of effects, including defects, a synergistic effect, change of d-band center of palladium, and surface strain.