Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone).
basic_science · Level V
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- Record sourced from PubMed, PMID 30226247.
- Also identified by DOI 10.1039/c8sm01777h.
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Abstract
We present an unexpected self-assembly of a glycoluril clip-poly(ε-caprolactone) conjugate in chloroform. The conjugate forms homodimer aggregates due to supramolecular interactions between glycoluril moieties, which was confirmed with MALDI-TOF-ms and 1H NMR. TEM revealed the formation of multilayered nanosized prism-shaped objects resembling tree bark in nature.