Evidence for magmatic carbon bias in <sup>14</sup>C dating of the Taupo and other major eruptions.

Holdaway, Richard N; Duffy, Brendan; Kennedy, Ben · Nat Commun · 2018

basic_science · Level V

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Abstract

Prehistoric timescales, volcanic hazard assessment, and understanding of volcanogenic climate events rely on accurate dating of prehistoric eruptions. Most late Quaternary eruptions are dated by <sup>14</sup>C measurements on material from close to the volcano that may be contaminated by geologic-sourced infinite-age carbon. Here we show that <sup>14</sup>C ages for the Taupo (New Zealand) First Millennium eruption are geographically arrayed, with oldest ages closer to the vent. The current eruption wiggle match date of 232 ± 5 years CE is amongst the oldest. We present evidence that the older, vent-proximal <sup>14</sup>C ages were biased by magmatic CO<sub>2</sub> degassed from groundwater, and that the Taupo eruption occurred decades to two centuries after 232 CE. Our reinterpretation implies that ages for other proximally-dated, unobserved, eruptions may also be too old. Plateauing or declining tree ring cellulose δ<sup>13</sup>C and Δ<sup>14</sup>C values near a volcano indicate magmatic influence and may allow forecasting of super-eruptions.