Flexible and stable high-energy lithium-sulfur full batteries with only 100% oversized lithium.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 30367063.
- Also identified by DOI 10.1038/s41467-018-06879-7 and PMC identifier 6203774.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Lightweight and flexible energy storage devices are urgently needed to persistently power wearable devices, and lithium-sulfur batteries are promising technologies due to their low mass densities and high theoretical capacities. Here we report a flexible and high-energy lithium-sulfur full battery device with only 100% oversized lithium, enabled by rationally designed copper-coated and nickel-coated carbon fabrics as excellent hosts for lithium and sulfur, respectively. These metallic carbon fabrics endow mechanical flexibility, reduce local current density of the electrodes, and, more importantly, significantly stabilize the electrode materials to reach remarkable Coulombic efficiency of >99.89% for a lithium anode and >99.82% for a sulfur cathode over 400 half-cell charge-discharge cycles. Consequently, the assembled lithium-sulfur full battery provides high areal capacity (3 mA h cm<sup>-2</sup>), high cell energy density (288 W h kg<sup>-1</sup> and 360 W h L<sup>-1</sup>), excellent cycling stability (260 cycles), and remarkable bending stability at a small radius of curvature (<1 mm).