A triply-responsive supramolecular vesicle fabricated by α-cyclodextrin based host-guest recognition and double dynamic covalent bonds.

Li, Shangyang; Chu, Xiaoxiao; Hao, Aiyou; Shang, Ningzhao; Wang, Chun · Soft Matter · 2018

basic_science · Level V

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Abstract

The supramolecular construction of multi-stimuli assemblies is a challenging task for prospective use. In this work, a novel supramolecular amphiphile was fabricated by introducing molecules with dynamic covalent bonds into host-guest inclusion. The amphiphile formed a vesicle, which was characterized by transmission electron microscopy (TEM), dynamic light scattering (DLS), 1H NMR and UV-vis spectra. Furthermore, the vesicular structure could be regulated by pH, light and redox reagent, and thus the loaded dye in the vesicles could be released in a controlled manner.

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