Hydrophobicity of surface-immobilised molecules influences architectures formed via interfacial self-assembly of nucleoside-based gelators.

Angelerou, Maria Galini Faidra; Yang, Bin; Arnold, Thomas; Rawle, Jonathan; Marlow, Maria; Zelzer, Mischa · Soft Matter · 2018

basic_science · Level V

Where this comes from

Abstract

Surface-mediated self-assembly has potential in biomaterial development but underlying rules governing surface-gelator interactions are poorly understood. Here, we correlate surface properties with structural characterization data of nucleoside-based gels obtained by GISAXS and GIWAXS and find that hydrophobicity descriptors (log P, polar surface area, aromaticity) are key predictors for the gel structures formed.