Room-temperature electrochemical water-gas shift reaction for high purity hydrogen production.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 30622261.
- Also identified by DOI 10.1038/s41467-018-07937-w and PMC identifier 6325145.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Traditional water-gas shift reaction provides one primary route for industrial production of clean-energy hydrogen. However, this process operates at high temperatures and pressures, and requires additional separation of H<sub>2</sub> from products containing CO<sub>2</sub>, CH<sub>4</sub> and residual CO. Herein, we report a room-temperature electrochemical water-gas shift process for direct production of high purity hydrogen (over 99.99%) with a faradaic efficiency of approximately 100%. Through rational design of anode structure to facilitate CO diffusion and PtCu catalyst to optimize CO adsorption, the anodic onset potential is lowered to almost 0 volts versus the reversible hydrogen electrode at room temperature and atmospheric pressure. The optimized PtCu catalyst achieves a current density of 70.0 mA cm<sup>-2</sup> at 0.6 volts which is over 12 times that of commercial Pt/C (40 wt.%) catalyst, and remains stable for even more than 475 h. This study opens a new and promising route of producing high purity hydrogen.