Ferromagnetism above 1000 K in a highly cation-ordered double-perovskite insulator Sr<sub>3</sub>OsO<sub>6</sub>.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 30755601.
- Also identified by DOI 10.1038/s41467-019-08440-6 and PMC identifier 6372617.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Magnetic insulators have wide-ranging applications, including microwave devices, permanent magnets and future spintronic devices. However, the record Curie temperature (TC), which determines the temperature range in which any ferri/ferromagnetic system remains stable, has stood still for over eight decades. Here we report that a highly B-site ordered cubic double-perovskite insulator, Sr3OsO6, has the highest TC (of ~1060 K) among all insulators and oxides; also, this is the highest magnetic ordering temperature in any compound without 3d transition elements. The cubic B-site ordering is confirmed by atomic-resolution scanning transmission electron microscopy. The electronic structure calculations elucidate a ferromagnetic insulating state with Jeff = 3/2 driven by the large spin-orbit coupling of Os6+ 5d2 orbitals. Moreover, the Sr3OsO6 films are epitaxially grown on SrTiO3 substrates, suggesting that they are compatible with device fabrication processes and thus promising for spintronic applications.