A Novel Hybrid-Layered Organic Phototransistor Enables Efficient Intermolecular Charge Transfer and Carrier Transport for Ultrasensitive Photodetection.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 30828883.
- Also identified by DOI 10.1002/adma.201900763.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
The interfacial charge effect is crucial for high-sensitivity organic phototransistors (OPTs), but conventional layered and hybrid OPTs have a trade-off in balancing the separation, transport, and recombination of photogenerated charges, consequently impacting the device performance. Herein, a novel hybrid-layered phototransistor (HL-OPT) is reported with significantly improved photodetection performance, which takes advantages of both the charge-trapping effect (CTE) and efficient carrier transport. The HL-OPT consisting of 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) as conduction channel, C8-BTBT:[6,6]-phenyl-C<sub>61</sub> -butyric acid methyl ester (PC<sub>61</sub> BM) bulk heterojunction as photoactive layer, and sandwiched MoO<sub>3</sub> interlayer as a charge-transport interlayer exhibits outstanding photodetection characteristics such as a photosensitivity (I<sub>light</sub> /I<sub>dark</sub> ) of 2.9 × 10<sup>6</sup> , photoresponsivity (R) of 8.6 × 10<sup>3</sup> A W<sup>-1</sup> , detectivity (D*) of 3.4 × 10<sup>14</sup> Jones, and external quantum efficiency of 3 × 10<sup>6</sup> % under weak light illumination of 32 µW cm<sup>-2</sup> . The mechanism and strategy described here provide new insights into the design and optimization of high-performance OPTs spanning the ultraviolet and near infrared (NIR) range as well as fundamental issues pertaining to the electronic and photonic properties of the devices.