Covalent Diamond-Graphite Bonding: Mechanism of Catalytic Transformation.
basic_science · Level V
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- Record sourced from PubMed, PMID 30883098.
- Also identified by DOI 10.1021/acsnano.9b00692 and PMC identifier 6482437.
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Abstract
Aberration-corrected transmission electron microscopy of the atomic structure of diamond-graphite interface after Ni-induced catalytic transformation reveals graphitic planes bound covalently to the diamond in the upright orientation. The covalent attachment, together with a significant volume expansion of graphite transformed from diamond, gives rise to uniaxial stress that is released through plastic deformation. We propose a comprehensive model explaining the Ni-mediated transformation of diamond to graphite and covalent bonding at the interface as well as the mechanism of relaxation of uniaxial stress. We also explain the mechanism of electrical transport through the graphitized surface of diamond. The result may thus provide a foundation for the catalytically driven formation of graphene-diamond nanodevices.