Functionalized Porous Aromatic Frameworks as High-Performance Adsorbents for the Rapid Removal of Boric Acid from Water.

Abstract

This study demonstrates that functionalized, highly porous polymers are promising for the adsorptive capture of boric acid, a neutral contaminant that is difficult to remove from seawater using conventional reverse osmosis membranes. Appending N-methyl-d-glucamine (NMDG) to the pore walls of high-surface-area porous aromatic frameworks (PAFs) yields the adsorbents PAF-1-NMDG and P2-NMDG in a simple two-step synthesis. The boron-selective PAFs demonstrate adsorption capacities that are up to 70% higher than those of a commercial boron-selective resin, Amberlite IRA743, and markedly faster adsorption rates, owing to their higher NMDG loadings and greater porosities relative to the resin. Remarkably, PAF-1-NMDG is able to reduce the boron concentration in synthetic seawater from 2.91 to <0.5 ppm in less than 3 min at an adsorbent loading of only 0.3 mg mL^-1 . The boron adsorption rate constants of both frameworks, determined via a pseudo-second-order rate model, represent the highest values reported in the literature-in most cases orders of magnitude higher than those of other boron-selective adsorbents. The frameworks can also be readily regenerated via mild acid/base treatment and maintain constant boron adsorption capacities for at least 10 regeneration cycles. These results highlight the numerous advantages of PAFs over traditional porous polymers in water treatment applications.