Sustainability-inspired cell design for a fully recyclable sodium ion battery.

Liu, Tiefeng; Zhang, Yaping; Chen, Chao; Lin, Zhan; Zhang, Shanqing; Lu, Jun · Nat Commun · 2019

basic_science · Level V

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Abstract

Large-scale applications of rechargeable batteries consume nonrenewable resources and produce massive amounts of end-of-life wastes, which raise sustainability concerns in terms of manufacturing, environmental, and ecological costs. Therefore, the recyclability and sustainability of a battery should be considered at the design stage by using naturally abundant resources and recyclable battery technology. Herein, we design a fully recyclable rechargeable sodium ion battery with bipolar electrode structure using Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> as an electrode material and aluminum foil as the shared current collector. Such a design allows exceptional sodium ion battery performance in terms of high-power correspondence and long-term stability and enables the recycling of ∼100% Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> and ∼99.1% elemental aluminum without the release of toxic wastes, resulting in a solid-component recycling efficiency of >98.0%. The successful incorporation of sustainability into battery design suggests that closed-loop recycling and the reutilization of battery materials can be achieved in next-generation energy storage technologies.