Femtosecond time-resolved two-photon photoemission studies of ultrafast carrier relaxation in Cu<sub>2</sub>O photoelectrodes.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 31068589.
- Also identified by DOI 10.1038/s41467-019-10143-x and PMC identifier 6506537.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Cuprous oxide (Cu<sub>2</sub>O) is a promising material for solar-driven water splitting to produce hydrogen. However, the relatively small accessible photovoltage limits the development of efficient Cu<sub>2</sub>O based photocathodes. Here, femtosecond time-resolved two-photon photoemission spectroscopy has been used to probe the electronic structure and dynamics of photoexcited charge carriers at the Cu<sub>2</sub>O surface as well as the interface between Cu<sub>2</sub>O and a platinum (Pt) adlayer. By referencing ultrafast energy-resolved surface sensitive spectroscopy to bulk data we identify the full bulk to surface transport dynamics for excited electrons rapidly localized within an intrinsic deep continuous defect band ranging from the whole crystal volume to the surface. No evidence of bulk electrons reaching the surface at the conduction band level is found resulting into a substantial loss of their energy through ultrafast trapping. Our results uncover main factors limiting the energy conversion processes in Cu<sub>2</sub>O and provide guidance for future material development.