Scaling growth rates for perovskite oxide virtual substrates on silicon.

Lapano, Jason; Brahlek, Matthew; Zhang, Lei; Roth, Joseph; Pogrebnyakov, Alexej; Engel-Herbert, Roman · Nat Commun · 2019

basic_science · Level V

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Abstract

The availability of native substrates is a cornerstone in the development of microelectronic technologies relying on epitaxial films. If native substrates are not available, virtual substrates - crystalline buffer layers epitaxially grown on a structurally dissimilar substrate - offer a solution. Realizing commercially viable virtual substrates requires the growth of high-quality films at high growth rates for large-scale production. We report the stoichiometric growth of SrTiO<sub>3</sub> exceeding 600 nm hr<sup>-1</sup>. This tenfold increase in growth rate compared to SrTiO<sub>3</sub> grown on silicon by conventional methods is enabled by a self-regulated growth window accessible in hybrid molecular beam epitaxy. Overcoming the materials integration challenge for complex oxides on silicon using virtual substrates opens a path to develop new electronic devices in the More than Moore era and silicon integrated quantum computation hardware.