Plasmonic Photocatalysis of Nitrous Oxide into N₂ and O₂ Using Aluminum-Iridium Antenna-Reactor Nanoparticles.

Abstract

Photocatalysis with optically active "plasmonic" nanoparticles is a growing field in heterogeneous catalysis, with the potential for substantially increasing efficiencies and selectivities of chemical reactions. Here, the decomposition of nitrous oxide (N₂O), a potent anthropogenic greenhouse gas, on illuminated aluminum-iridium (Al-Ir) antenna-reactor plasmonic photocatalysts is reported. Under resonant illumination conditions, N₂ and O₂ are the only observable decomposition products, avoiding the problematic generation of NO_<i>x</i> species observed using other approaches. Because no appreciable change to the apparent activation energy was observed under illumination, the primary reaction enhancement mechanism for Al-Ir is likely due to photothermal heating rather than plasmon-induced hot-carrier contributions. This light-based approach can induce autocatalysis for rapid N₂O conversion, a process with highly promising potential for applications in N₂O abatement technologies, satellite propulsion, or emergency life-support systems in space stations and submarines.