Best practices and benchmarks for intact protein analysis for top-down mass spectrometry.

Donnelly, Daniel P; Rawlins, Catherine M; DeHart, Caroline J; Fornelli, Luca; Schachner, Luis F; Lin, Ziqing; Lippens, Jennifer L; Aluri, Krishna C et al. · Nat Methods · 2019

review · Level V

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Abstract

One gene can give rise to many functionally distinct proteoforms, each of which has a characteristic molecular mass. Top-down mass spectrometry enables the analysis of intact proteins and proteoforms. Here members of the Consortium for Top-Down Proteomics provide a decision tree that guides researchers to robust protocols for mass analysis of intact proteins (antibodies, membrane proteins and others) from mixtures of varying complexity. We also present cross-platform analytical benchmarks using a protein standard sample, to allow users to gauge their proficiency.

Medical subject headings