Possible Excitonic Insulating Phase in Quantum-Confined Sb Nanoflakes.

Li, Zhi; Nadeem, Muhammad; Yue, Zengji; Cortie, David; Fuhrer, Michael; Wang, Xiaolin · Nano Lett · 2019

basic_science · Level V

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Abstract

In the 1960s, it was proposed that in small indirect band-gap materials, excitons can spontaneously form because the density of carriers is too low to screen the attractive Coulomb interaction between electrons and holes. The result is a novel strongly interacting insulating phase known as an excitonic insulator. Here we employ scanning tunnelling microscopy (STM) and spectroscopy (STS) to show that the enhanced Coulomb interaction in quantum-confined elemental Sb nanoflakes drives the system to the excitonic insulator state. The unique feature of the excitonic insulator, a charge density wave (CDW) without periodic lattice distortion, is directly observed. Furthermore, STS shows a gap induced by the CDW near the Fermi surface. Our observations suggest that the Sb(110) nanoflake is an excitonic insulator.