Diagonal nematicity in the pseudogap phase of HgBa<sub>2</sub>CuO<sub>4+δ</sub>.

Murayama, H; Sato, Y; Kurihara, R; Kasahara, S; Mizukami, Y; Kasahara, Y; Uchiyama, H; Yamamoto, A et al. · Nat Commun · 2019

basic_science · Level V

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Abstract

The pseudogap phenomenon in the cuprates is arguably the most mysterious puzzle in the field of high-temperature superconductivity. The tetragonal cuprate HgBa<sub>2</sub>CuO<sub>4+δ</sub>, with only one CuO<sub>2</sub> layer per primitive cell, is an ideal system to tackle this puzzle. Here, we measure the magnetic susceptibility anisotropy within the CuO<sub>2</sub> plane with exceptionally high-precision magnetic torque experiments. Our key finding is that a distinct two-fold in-plane anisotropy sets in below the pseudogap temperature T<sup>*</sup>, which provides thermodynamic evidence for a nematic phase transition with broken four-fold symmetry. Surprisingly, the nematic director orients along the diagonal direction of the CuO<sub>2</sub> square lattice, in sharp contrast to the bond nematicity along the Cu-O-Cu direction. Another remarkable feature is that the enhancement of the diagonal nematicity with decreasing temperature is suppressed around the temperature at which short-range charge-density-wave formation occurs. Our result suggests a competing relationship between diagonal nematic and charge-density-wave order in HgBa<sub>2</sub>CuO<sub>4+δ</sub>.