Realizing nearly-free-electron like conduction band in a molecular film through mediating intermolecular van der Waals interactions.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 31358744.
- Also identified by DOI 10.1038/s41467-019-11300-y and PMC identifier 6662711.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Collective molecular physical properties can be enhanced from their intrinsic characteristics by templating at material interfaces. Here we report how a black phosphorous (BP) substrate concatenates a nearly-free-electron (NFE) like conduction band of a C<sub>60</sub> monolayer. Scanning tunneling microscopy reveals the C<sub>60</sub> lowest unoccupied molecular orbital (LUMO) band is strongly delocalized in two-dimensions, which is unprecedented for a molecular semiconductor. Experiment and theory show van der Waals forces between C<sub>60</sub> and BP reduce the inter-C<sub>60</sub> distance and cause mutual orientation, thereby optimizing the π-π wave function overlap and forming the NFE-like band. Electronic structure and carrier mobility calculations predict that the NFE band of C<sub>60</sub> acquires an effective mass of 0.53-0.70 m<sub>e</sub> (m<sub>e</sub> is the mass of free electrons), and has carrier mobility of ~200 to 440 cm<sup>2</sup>V<sup>-1</sup>s<sup>-1</sup>. The substrate-mediated intermolecular van der Waals interactions provide a route to enhance charge delocalization in fullerenes and other organic semiconductors.