Molecular theory of a ferromagnetic nematic liquid crystal.

Abstract

We employ a version of classical density functional theory to study the phase behavior of a simple model liquid crystal in an external field. The uniaxially symmetric molecules have a spherically symmetric core with superimposed orientation-dependent attractions. The interaction between the cores consists of a hard-sphere repulsion plus an isotropic square-well attraction. The anisotropic part of the interaction potential allows for the formation of a uniaxially symmetric nematic phase. The orientation of the molecules couples to an external polar field. The external field is capable of rotating the nematic director n[over ̂] in the x-z plane. The field is also capable of changing the topology of the phase diagram in that it suppresses the phase coexistence between an isotropic liquid and a nematic phase observed in the absence of the field. We study the transition from an unpolar to a polar nematic phase in terms of the orientation-distribution function (odf), nematic and polar order parameters, and components of n[over ̂]. If represented suitably the odf allows us to study orientational changes during the switching process between nonpolar and polar nematic phases. We also give a simple argument that explains why nematic order is lost whereas polar order persists up to the gas-liquid critical point along the coexistence curve. We also discuss the relevance of our theory for future experimental studies.