Synthesis of magnesium-nitrogen salts of polynitrogen anions.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 31586062.
- Also identified by DOI 10.1038/s41467-019-12530-w and PMC identifier 6778147.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
The synthesis of polynitrogen compounds is of fundamental importance due to their potential as environmentally-friendly high energy density materials. Attesting to the intrinsic difficulties related to their formation, only three polynitrogen ions, bulk stabilized as salts, are known. Here, magnesium and molecular nitrogen are compressed to about 50 GPa and laser-heated, producing two chemically simple salts of polynitrogen anions, MgN<sub>4</sub> and Mg<sub>2</sub>N<sub>4</sub>. Single-crystal X-ray diffraction reveals infinite anionic polythiazyl-like 1D N-N chains in the crystal structure of MgN<sub>4</sub> and cis-tetranitrogen N<sub>4</sub><sup>4-</sup> units in the two isosymmetric polymorphs of Mg<sub>2</sub>N<sub>4</sub>. The cis-tetranitrogen units are found to be recoverable at atmospheric pressure. Our results respond to the quest for polynitrogen entities stable at ambient conditions, reveal the potential of employing high pressures in their synthesis and enrich the nitrogen chemistry through the discovery of other nitrogen species, which provides further possibilities to design improved polynitrogen arrangements.