Electric dipole effect in PdCoO<sub>2</sub>/β-Ga<sub>2</sub>O<sub>3</sub> Schottky diodes for high-temperature operation.
basic_science · Level V
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- Record sourced from PubMed, PMID 31667346.
- Also identified by DOI 10.1126/sciadv.aax5733 and PMC identifier 6799984.
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Abstract
High-temperature operation of semiconductor devices is widely demanded for switching/sensing purposes in automobiles, plants, and aerospace applications. As alternatives to conventional Si-based Schottky diodes usable only at 200°C or less, Schottky interfaces based on wide-bandgap semiconductors have been extensively studied to realize a large Schottky barrier height that makes high-temperature operation possible. Here, we report a unique crystalline Schottky interface composed of a wide-gap semiconductor β-Ga<sub>2</sub>O<sub>3</sub> and a layered metal PdCoO<sub>2</sub>. At the thermally stable all-oxide interface, the polar layered structure of PdCoO<sub>2</sub> generates electric dipoles, realizing a large Schottky barrier height of ~1.8 eV, well beyond the 0.7 eV expected from the basal Schottky-Mott relation. Because of the naturally formed homogeneous electric dipoles, this junction achieved current rectification with a large on/off ratio approaching 10<sup>8</sup> even at a high temperature of 350°C. The exceptional performance of the PdCoO<sub>2</sub>/β-Ga<sub>2</sub>O<sub>3</sub> Schottky diodes makes power/sensing devices possible for extreme environments.