The J_eff = 1/2 Antiferromagnet Sr₂ IrO₄ : A Golden Avenue toward New Physics and Functions.

Abstract

Iridates have been providing a fertile ground for studying emergent phases of matter that arise from the delicate interplay of various fundamental interactions with approximate energy scale. Among these highly focused quantum materials, the perovskite Sr₂ IrO₄ , which belongs to the Ruddlesden-Popper series, stands out and has been intensively addressed in the last decade, since it hosts a novel J_eff = 1/2 state that is a profound manifestation of strong spin-orbit coupling. Moreover, the J_eff = 1/2 state represents a rare example of iridates that is better understood both theoretically and experimentally. Here, Sr₂ IrO₄ is taken as an example to review the recent advances of the J_eff = 1/2 state in two aspects: materials fundamentals and functionality potentials. In the fundamentals part, the basic issues for the layered canted antiferromagnetic order of the J_eff = 1/2 magnetic moments in Sr₂ IrO₄ are illustrated, and then the progress of the antiferromagnetic order modulation through diverse routes is highlighted. Subsequently, for the functionality potentials, fascinating properties such as atomic-scale giant magnetoresistance, anisotropic magnetoresistance, and nonvolatile memory, are addressed. To conclude, prospective remarks and an outlook are given.