Copper Silicide Nanowires as Hosts for Amorphous Si Deposition as a Route to Produce High Capacity Lithium-Ion Battery Anodes.

Abstract

Herein, copper silicide (Cu₁₅Si₄) nanowires (NWs) grown in high densities from a metallic Cu substrate are utilized as nanostructured hosts for amorphous silicon (aSi) deposition. The conductive Cu₁₅Si₄ NW scaffolds offer an increased surface area, versus planar substrates, and enable the preparation of high capacity Li-ion anodes consisting of a nanostructured active material. The formation method involves a two-step process, where Cu₁₅Si₄ nanowires are synthesized from a Cu substrate via a solvent vapor growth (SVG) approach followed by the plasma-enhanced chemical vapor deposition (PECVD) of aSi. These binder-free anodes are investigated in half-cell (versus Li-foil) and full-cell (versus LCO) configurations with discharge capacities greater than 2000 mAh/g retained after 200 cycles (half-cell) and reversible capacities of 1870 mAh/g exhibited after 100 cycles (full-cell). A noteworthy rate capability is also attained where capacities of up to 1367 mAh/g and 1520 mAh/g are exhibited at 5C in half-cell and full-cell configurations, respectively, highlighting the active material's promise for fast charging and high power applications. The anode material is characterized prior to cycling and after 1, 25, and 100 charge/discharge cycles, by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), to track the effects of cycling on the material.