Curvature affects electrolyte relaxation: Studies of spherical and cylindrical electrodes.
basic_science · Level V
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- Record sourced from PubMed, PMID 31771008.
- Also identified by DOI 10.1103/PhysRevE.100.042602.
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Abstract
With two minimal models, I study how electrode curvature affects the response of electrolytes to applied electrostatic potentials. For flat electrodes, Bazant et al. [Phys. Rev. E 70, 021506 (2004)PLEEE81539-375510.1103/PhysRevE.70.021506] popularized the RC timescale λ_{D}L/D, with λ_{D} being the Debye length, 2L the electrode separation, and D the ionic diffusivity. For thin electric double layers near concentric spherical and coaxial cylindrical electrodes, I show here that equivalent circuit models again predict the correct ionic relaxation timescales. Importantly, these timescales explicitly depend on both electrode radii, not simply on their difference.