A High-Voltage, Dendrite-Free, and Durable Zn-Graphite Battery.
basic_science · Level V
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- Record sourced from PubMed, PMID 31788883.
- Also identified by DOI 10.1002/adma.201905681.
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Abstract
The intrinsic advantages of metallic Zn, like high theoretical capacity (820 mAh g<sup>-1</sup> ), high abundance, low toxicity, and high safety have driven the recent booming development of rechargeable Zn batteries. However, the lack of high-voltage electrolyte and cathode materials restricts the cell voltage mostly to below 2 V. Moreover, dendrite formation and the poor rechargeability of the Zn anode hinder the long-term operation of Zn batteries. Here a high-voltage and durable Zn-graphite battery, which is enabled by a LiPF<sub>6</sub> -containing hybrid electrolyte, is reported. The presence of LiPF<sub>6</sub> efficiently suppresses the anodic oxidation of Zn electrolyte and leads to a super-wide electrochemical stability window of 4 V (vs Zn/Zn<sup>2+</sup> ). Both dendrite-free Zn plating/stripping and reversible dual-anion intercalation into the graphite cathode are realized in the hybrid electrolyte. The resultant Zn-graphite battery performs stably at a high voltage of 2.8 V with a record midpoint discharge voltage of 2.2 V. After 2000 cycles at a high charge-discharge rate, high capacity retention of 97.5% is achieved with ≈100% Coulombic efficiency.