Microphase separation in a two-dimensional colloidal system with competing attractive critical Casimir and repulsive magnetic dipole interactions.

Abstract

We propose and study theoretically a colloidal system in two dimensions with attractive critical Casimir and repulsive magnetic dipole forces, wherein the strength of attraction and repulsion can be easily and independently tuned by adjusting the temperature and an external magnetic field, respectively. We expect this setup to be experimentally accessible and are confident that it can serve to deepen our understanding of the mechanisms behind microphase separation due to competing interactions. We develop a density functional theory for our model and present first results of our calculations in the form of a phase diagram for fixed temperature, but varying magnetic fields and bulk densities. For certain values of these parameters, we are able to confirm the existence of thermodynamically stable inhomogeneous density profiles in the bulk, such as parallel lamellar stripes, as well as clusters and voids on a hexagonal lattice.