Spontaneous shrinkage of droplet on a wetting surface in the phase-field model.

Abstract

Phase-field theory is widely used to model multiphase flow. The fact that a drop can shrink or grow spontaneously due to the redistribution of interface and bulk energies to minimize the system energy may produce ill effects on the simulation. In this Rapid Communication, the spontaneous behavior of a drop on a partially wetting surface is investigated. It is found that there exists a critical radius dependent on the contact angle, the domain size, and the interface width, below which the drop will eventually disappear. In particular, the critical radius can be very large when the surface becomes very hydrophilic. The theoretical prediction of the critical radius is verified numerically by simulating a drop on a surface with various contact angles, the domain sizes, and the interface widths.