A Universal Lab-on-Salt-Particle Approach to 2D Single-Layer Ordered Mesoporous Materials.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 31995257.
- Also identified by DOI 10.1002/adma.201906653.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
The advantages of existing ordered mesoporous materials have not yet been fully realized, due to their limited accessibility of in-pore surface and long mass-diffusion length. A general, controllable, and scalable synthesis of a family of two-dimensional (2D) single-layer ordered mesoporous materials (SOMMs) with completely exposed mesopore channels, significantly improved mass diffusion, and diverse framework composition is reported here. The SOMMs are synthesized via a surface-limited cooperative assembly (SLCA) on water-removable substrates of inorganic salts (e.g., NaCl), combined with vacuum filtration. As a proof of concept, the obtained CeO<sub>2</sub> -based SOMMs show superior catalytic performance in CO oxidation with high conversion efficiency, ≈33 times higher than that of conventional bulk mesoporous CeO<sub>2</sub> . This SLCA is a promising approach for developing next-generation porous materials for various applications.