Weak functional group interactions revealed through metal-free active template rotaxane synthesis.

Tian, Chong; Fielden, Stephen D P; Whitehead, George F S; Vitorica-Yrezabal, Iñigo J; Leigh, David A · Nat Commun · 2020

basic_science · Level V

Where this comes from

Abstract

Modest functional group interactions can play important roles in molecular recognition, catalysis and self-assembly. However, weakly associated binding motifs are often difficult to characterize. Here, we report on the metal-free active template synthesis of [2]rotaxanes in one step, up to 95% yield and >100:1 rotaxane:axle selectivity, from primary amines, crown ethers and a range of C=O, C=S, S(=O)<sub>2</sub> and P=O electrophiles. In addition to being a simple and effective route to a broad range of rotaxanes, the strategy enables 1:1 interactions of crown ethers with various functional groups to be characterized in solution and the solid state, several of which are too weak - or are disfavored compared to other binding modes - to be observed in typical host-guest complexes. The approach may be broadly applicable to the kinetic stabilization and characterization of other weak functional group interactions.