Clusterization of self-propelled particles in a two-component system.

Abstract

We consider a mixture of active solute molecules in a suspension of passive solvent particles comprising a thermal bath. The solute molecules are considered to be extended objects with two chemically distinct heads, one head of which having chemical affinity towards the solvent particles. The coupled Langevin equations for the solvent particles along with the equations governing the dynamics of active molecules are numerically simulated to show how the active molecules self-assemble to form clusters which remain in dynamic equilibrium with the free solute molecules. We observe an interesting crossover at an intermediate time in the variation of the order parameter with time when the temperature of the bath is changed signifying the differential behavior of clusterization below and above the crossover time associated with a transition between a thermodynamic and a quasithermodynamic regime. Enthalpy-entropy compensation in the formation of clusters below the crossover is demonstrated.