An ultrastable lithium metal anode enabled by designed metal fluoride spansules.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 32181364.
- Also identified by DOI 10.1126/sciadv.aaz3112 and PMC identifier 7060059.
- Licence recorded as CC BY-NC.
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Abstract
The lithium metal anode (LMA) is considered as a promising star for next-generation high-energy density batteries but is still hampered by the severe growth of uncontrollable lithium dendrites. Here, we design "spansules" made of NaMg(Mn)F<sub>3</sub>@C core@shell microstructures as the matrix for the LMA, which can offer a long-lasting release of functional ions into the electrolyte. By the assistance of cryogenic transmission electron microscopy, we reveal that an in situ-formed metal layer and a unique LiF-involved bilayer structure on the Li/electrolyte interface would be beneficial for effectively suppressing the growth of lithium dendrites. As a result, the spansule-modified anode affords a high Coulombic efficiency of 98% for over 1000 cycles at a current density of 2 mA cm<sup>-2</sup>, which is the most stable LMA reported so far. When coupling this anode with the Li[Ni<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>]O<sub>2</sub> cathode, the practical full cell further exhibits highly improved capacity retention after 500 cycles.