Molecular-statistical theory of ferromagnetic liquid crystal suspensions.

Abstract

A tensor variant of molecular-statistical theory is developed, within the framework of which it is possible to describe the appearance of spontaneous magnetization of anisotropic ferromagnetic nanoparticles dispersed in a nematic liquid crystal. Along with the tensor order parameters characterizing the orientational ordering of the liquid crystal and dispersed anisometric particles, the vector order parameter determining the magnetization of the ensemble of particles is additionally taken into account. A comparison between the previously known phenomenological theories of ferronematics and the proposed molecular-statistical theory is made. Phase diagrams of the suspension are constructed and the mean-field theory parameters are calculated on the basis of experimental data available in the literature.