Structure-based design of antiviral drug candidates targeting the SARS-CoV-2 main protease.

Dai, Wenhao; Zhang, Bing; Jiang, Xia-Ming; Su, Haixia; Li, Jian; Zhao, Yao; Xie, Xiong; Jin, Zhenming et al. · Science · 2020

basic_science · Level V

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Abstract

SARS-CoV-2 (severe acute respiratory syndrome coronavirus 2) is the etiological agent responsible for the global COVID-19 (coronavirus disease 2019) outbreak. The main protease of SARS-CoV-2, M<sup>pro</sup>, is a key enzyme that plays a pivotal role in mediating viral replication and transcription. We designed and synthesized two lead compounds (<b>11a</b> and <b>11b</b>) targeting M<sup>pro</sup> Both exhibited excellent inhibitory activity and potent anti-SARS-CoV-2 infection activity. The x-ray crystal structures of SARS-CoV-2 M<sup>pro</sup> in complex with <b>11a</b> or <b>11b</b>, both determined at a resolution of 1.5 angstroms, showed that the aldehyde groups of <b>11a</b> and <b>11b</b> are covalently bound to cysteine 145 of M<sup>pro</sup> Both compounds showed good pharmacokinetic properties in vivo, and <b>11a</b> also exhibited low toxicity, which suggests that these compounds are promising drug candidates.

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