Room-temperature chemical synthesis of C₂.

Abstract

Diatomic carbon (C₂) is historically an elusive chemical species. It has long been believed that the generation of C₂ requires extremely high physical energy, such as an electric carbon arc or multiple photon excitation, and so it has been the general consensus that the inherent nature of C₂ in the ground state is experimentally inaccessible. Here, we present the chemical synthesis of C₂ from a hypervalent alkynyl-λ³-iodane in a flask at room temperature or below, providing experimental evidence to support theoretical predictions that C₂ has a singlet biradical character with a quadruple bond, thus settling a long-standing controversy between experimental and theoretical chemists, and that C₂ serves as a molecular element in the bottom-up chemical synthesis of nanocarbons such as graphite, carbon nanotubes, and C₆₀.