Infrared Nanoimaging of Surface Plasmons in Type-II Dirac Semimetal PtTe<sub>2</sub> Nanoribbons.

Hu, Xin; Wong, Kin Ping; Zeng, Longhui; Guo, Xuyun; Liu, Tong; Zhang, Lei; Chen, Qin; Zhang, Xuefeng et al. · ACS Nano · 2020

basic_science · Level V

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Abstract

Topological Dirac semimetals made of two-dimensional transition-metal dichalcogenides (TMDCs) have attracted enormous interest for use in electronic and optoelectronic devices because of their electron transport properties. As van der Waals materials with a strong interlayer interaction, these semimetals are expected to support layer-dependent plasmonic polaritons yet to be revealed experimentally. Here, we demonstrate the apparent retardation and attenuation of mid-infrared (MIR) plasmonic waves in type-II Dirac semimetal platinum tellurium (PtTe<sub>2</sub>) nanoribbons and nanoflakes by near-field nanoimaging. The attenuated dispersion relations for the plasmonic modes in the PtTe<sub>2</sub> nanoribbons (15-25 nm thick) extracted from the near-field standing-wave patterns are applied for the fitting of PtTe<sub>2</sub> permittivity in the MIR regime, indicating that both free carriers and Dirac fermions are involved in MIR light-matter interaction in PtTe<sub>2</sub>. The annihilation of plasmonic modes in the ultrathin (<10 nm) PtTe<sub>2</sub> is observed and analyzed, which manifests no near-field resonant pattern due to the intrinsic layer-dependent optoelectronic properties of PtTe<sub>2</sub>. These results could pave a potential wave for MIR photodetection and modulation with TMDC semimetals.