Direct and indirect Z-scheme heterostructure-coupled photosystem enabling cooperation of CO<sub>2</sub> reduction and H<sub>2</sub>O oxidation.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 32546728.
- Also identified by DOI 10.1038/s41467-020-16742-3 and PMC identifier 7297725.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
The stoichiometric photocatalytic reaction of CO<sub>2</sub> with H<sub>2</sub>O is one of the great challenges in photocatalysis. Here, we construct a Cu<sub>2</sub>O-Pt/SiC/IrO<sub>x</sub> composite by a controlled photodeposition and then an artificial photosynthetic system with Nafion membrane as diaphragm separating reduction and oxidation half-reactions. The artificial system exhibits excellent photocatalytic performance for CO<sub>2</sub> reduction to HCOOH and H<sub>2</sub>O oxidation to O<sub>2</sub> under visible light irradiation. The yields of HCOOH and O<sub>2</sub> meet almost stoichiometric ratio and are as high as 896.7 and 440.7 μmol g<sup>-1</sup> h<sup>-1</sup>, respectively. The high efficiencies of CO<sub>2</sub> reduction and H<sub>2</sub>O oxidation in the artificial system are attributed to both the direct Z-scheme electronic structure of Cu<sub>2</sub>O-Pt/SiC/IrO<sub>x</sub> and the indirect Z-scheme spatially separated reduction and oxidation units, which greatly prolong lifetime of photogenerated electrons and holes and prevent the backward reaction of products. This work provides an effective and feasible strategy to increase the efficiency of artificial photosynthesis.