Validity of path thermodynamics in reactive systems.
basic_science · Level V
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- Record sourced from PubMed, PMID 32575179.
- Also identified by DOI 10.1103/PhysRevE.101.052135.
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Abstract
Path thermodynamic formulation of nonequilibrium reactive systems is considered. It is shown through simple practical examples that this approach can lead to results that contradict well established thermodynamic properties of such systems. Rigorous mathematical analysis confirming this fact is presented.