Viscous-viscoelastic correspondence principle for Brownian motion.

Abstract

Motivated by the classical expressions of the mean-square displacement and the velocity autocorrelation function of Brownian particles either suspended in a Newtonian viscous fluid or trapped in a harmonic potential, we show that for all timescales the mean-square displacement of Brownian microspheres with mass m and radius R suspended in any linear, isotropic viscoelastic material is identical to the creep compliance of a linear mechanical network that is a parallel connection of the linear viscoelastic material with an inerter with distributed inertance m_{R}=m/6πR. The synthesis of this mechanical network leads to the statement of a viscous-viscoelastic correspondence principle for Brownian motion which simplifies appreciably the calculations of the mean-square displacement and the velocity autocorrelation function of Brownian particles suspended in viscoelastic materials where inertia effects are non-negligible at longer timescales. The viscous-viscoelastic correspondence principle established in this paper by introducing the concept of the inerter is equivalent to the viscous-viscoelastic analogy adopted by Mason and Weitz [T. G. Mason and D. A. Weitz, Phys. Rev. Lett. 74, 1250 (1995)10.1103/PhysRevLett.74.1250].