High-loading single Pt atom sites [Pt-O(OH) <i><sub>x</sub></i> ] catalyze the CO PROX reaction with high activity and selectivity at mild conditions.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 32596455.
- Also identified by DOI 10.1126/sciadv.aba3809 and PMC identifier 7299615.
- Licence recorded as CC BY-NC.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
The preferential oxidation of CO (PROX) in hydrogen-rich fuel gas streams is an attractive option to remove CO while effectively conserving energy and H<sub>2</sub>. However, high CO conversion with concomitant high selectivity to CO<sub>2</sub> but not H<sub>2</sub>O is challenging. Here, we report the synthesis of high-loading single Pt atom (2.0 weight %) catalysts with oxygen-bonded alkaline ions that stabilize the cationic Pt. The synthesis is performed in aqueous solution and achieves high Pt atom loadings in a single-step incipient wetness impregnation of alumina or silica. Promisingly, these catalysts have high CO PROX selectivity even at high CO conversion (~99.8% conversion, 70% selectivity at 110°C) and good stability under reaction conditions. These findings pave the way for the design of highly efficient single-atom catalysts, elucidate the role of ─OH species in CO oxidation, and confirm the absence of a support effect for our case.