Supersoft elasticity and slow dynamics of isotropic-genesis polydomain liquid crystal elastomers investigated by loading- and strain-rate-controlled tests.

Abstract

The supersoft elasticity and slow dynamics of isotropic-genesis polydomain nematic elastomers are investigated by loading- and strain-rate-controlled tests. Loading-controlled tests reveal the stretching-driven polydomain-to-monodomain (PM) transition under true equilibrium condition without viscoelastic (time) effect. The equilibrium PM transition is observed as a discontinuous dimensional change at a threshold stress with extremely small magnitude (σ_{PM}^{∞}≈1kPa). The mechanical work required for 80% elongation of the elastomer accompanying the PM transition is only 2% of that required in the high-temperature isotropic state, reflecting the supersoft elasticity effect. The dimensional growth rate (R) under constant loading becomes low as the imposed stress (σ_{0}) approaches σ_{PM}^{∞}. The dependency of the dimension on the reduced time (Rt) is, however, independent of σ_{0}. In the strain-rate (ɛ[over ̇]) controlled tests, the stress-stretch curves show a plateau region characteristic of the PM transition in a finite range of stretch, which is equivalent to the discontinuous stretch in the loading-controlled tests. The plateau stress σ_{pl} significantly decreases with decreasing ɛ[over ̇], whereas the σ_{pl} at the practically accessible low strain rate (on the order of 10^{-4}s^{-1} ) is still significantly higher than σ_{PM}^{∞}. The dependency of σ_{pl} on ɛ[over ̇] is almost similar to the dependency of σ_{0} on R in the loading-controlled tests. This similarity signifies that the two types of tests with different controlled stimuli are governed by the same dynamics of the local director.