Quasi-metal Microwave Route to MoN and Mo<sub>2</sub>C Ultrafine Nanocrystalline Hollow Spheres as Surface-Enhanced Raman Scattering Substrates.
basic_science · Level V
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- Record sourced from PubMed, PMID 32931250.
- Also identified by DOI 10.1021/acsnano.0c05935.
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Abstract
MoN and Mo<sub>2</sub>C are important functional materials; however, due to the high activation energy barrier in their nucleation, their synthesis generally requires harsh conditions such as high temperature (>1000 °C) and high pressure (several GPa). The extreme conditions also hinder the acquisition of their ultrafine nanostructures. Herein, we report that MoN and Mo<sub>2</sub>C hollow spheres with large surface area (108.7-125.6 m<sup>2</sup> g<sup>-1</sup>) and ultrafine nanoparticles (2-5 nm) are prepared by a quasi-metal-based microwave route under mild conditions. MoO<sub>2</sub> hollow spheres are used as a quasi-metallic microwave absorbing medium as well as a molybdenum source and template simultaneously. The MoN and Mo<sub>2</sub>C ultrafine nanocrystalline hollow spheres exhibit strong localized surface plasmon resonance, high photothermal conversion efficiency, and strong surface-enhanced Raman scattering effects. Highly crystalline MoS<sub>2</sub> nanosheet hollow spheres can also be obtained by this method, indicating its universality. The present work provides an effective strategy for the rapid and mild preparation of ultrafine nanocrystalline transition metal nitrides and carbides with ultrahigh activation energy.