Modulated structure determination and ion transport mechanism of oxide-ion conductor CeNbO<sub>4+δ</sub>.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 32958759.
- Also identified by DOI 10.1038/s41467-020-18481-x and PMC identifier 7506534.
- Licence recorded as CC BY.
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Abstract
CeNbO<sub>4+δ</sub>, a family of oxygen hyperstoichiometry materials with varying oxygen content (CeNbO<sub>4</sub>, CeNbO<sub>4.08</sub>, CeNbO<sub>4.25</sub>, CeNbO<sub>4.33</sub>) that shows mixed electronic and oxide ionic conduction, has been known for four decades. However, the oxide ionic transport mechanism has remained unclear due to the unknown atomic structures of CeNbO<sub>4.08</sub> and CeNbO<sub>4.33</sub>. Here, we report the complex (3 + 1)D incommensurately modulated structure of CeNbO<sub>4.08</sub>, and the supercell structure of CeNbO<sub>4.33</sub> from single nanocrystals by using a three-dimensional electron diffraction technique. Two oxide ion migration events are identified in CeNbO<sub>4.08</sub> and CeNbO<sub>4.25</sub> by molecular dynamics simulations, which was a synergic-cooperation knock-on mechanism involving continuous breaking and reformation of Nb<sub>2</sub>O<sub>9</sub> units. However, the excess oxygen in CeNbO<sub>4.33</sub> hardly migrates because of the high concentration and the ordered distribution of the excess oxide ions. The relationship between the structure and oxide ion migration for the whole series of CeNbO<sub>4+δ</sub> compounds elucidated here provides a direction for the performance optimization of these compounds.