Longitudinal unzipping of 2D transition metal dichalcogenides.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 33024113.
- Also identified by DOI 10.1038/s41467-020-18810-0 and PMC identifier 7538978.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Unzipping of the basal plane offers a valuable pathway to uniquely control the material chemistry of 2D structures. Nonetheless, reliable unzipping has been reported only for graphene and phosphorene thus far. The single elemental nature of those materials allows a straightforward understanding of the chemical reaction and property modulation involved with such geometric transformations. Here we report spontaneous linear ordered unzipping of bi-elemental 2D MX<sub>2</sub> transition metal chalcogenides as a general route to synthesize 1D nanoribbon structures. The strained metallic phase (1T') of MX<sub>2</sub> undergoes highly specific longitudinal unzipping owing to the self-linearized oxygenation at chalcogenides. Stable dispersions of 1T' MoS<sub>2</sub> nanoribbons with widths of 10-120 nm and lengths up to ~4 µm are produced in water. Edge abundant 1T' MoS<sub>2</sub> nanoribbons reveal the hidden potential of idealized electrocatalysis for hydrogen evolution reactions at a competitive level with the precious Pt catalyst.