Area-Selective Atomic Layer Deposition of Metal Oxides on DNA Nanostructures and Its Applications.

Hui, Liwei; Nixon, Rachel; Tolman, Nathan; Mukai, Jason; Bai, Ruobing; Wang, Risheng; Liu, Haitao · ACS Nano · 2020

basic_science · Level V

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Abstract

We demonstrate area-selective atomic layer deposition (ALD) of oxides on DNA nanostructures. Area-selective ALD of Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, and HfO<sub>2</sub> was successfully achieved on both 2D and 3D DNA nanostructures deposited on a polystyrene (PS) substrate. The resulting DNA-inorganic hybrid structure was used as a hard mask to achieve deep etching of a Si wafer for antireflection applications. ALD is a widely used process in coating and thin film deposition; our work points to a way to pattern oxide materials using DNA templates and to enhance the chemical/physical stability of DNA nanostructures for applications in surface engineering.

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