A sandwich-type cluster containing Ge@Pd<sub>3</sub> planar fragment flanked by aromatic nonagermanide caps.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 33082326.
- Also identified by DOI 10.1038/s41467-020-19079-z and PMC identifier 7575547.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
Sandwich-type clusters with the planar fragment containing a heterometallic sheet have remained elusive. In this work, we introduce the [K(2,2,2-crypt)]<sub>4</sub>{(Ge<sub>9</sub>)<sub>2</sub>[η<sup>6</sup>-Ge(PdPPh<sub>3</sub>)<sub>3</sub>]} complex that contains a heterometallic sandwich fragment. The title compound is structurally characterized by means of single-crystal X-ray diffraction, which reveals the presence of an unusual heteroatomic metal planar fragment Ge@Pd<sub>3</sub>. The planar fragment contains a rare formal zerovalent germanium core and a peculiar bonding mode of sp<sup>2</sup>-Ge@(PdPPh<sub>3</sub>)<sub>3</sub> trigonal planar structure, whereas the nonagermanide fragments act as capping ligands. The chemical bonding pattern of the planar fragment consists of three 2c-2e Pd-Ge σ-bonds attaching Pd atoms to the core Ge atom, while the binding between the planar fragment and the aromatic Ge<sub>9</sub> ligands is provided by six 2c-2e Pd-Ge σ-bonds and two delocalized 4c-2e σ-bonds. The synthesized cluster represents a rare example of a sandwich compound with the heteroatomic metal planar fragment and inorganic aromatic capping ligands.