Dynamic Surface Reconstruction of Single-Atom Bimetallic Alloy under <i>Operando</i> Electrochemical Conditions.

Abstract

The atomic-level understanding of the dynamic evolution of the surface structure of bimetallic nanoparticles under industrially relevant <i>operando</i> conditions provides a key guide for improving their catalytic performance. Here, we exploit <i>operando</i> X-ray absorption fine structure spectroscopy to determine the dynamic surface reconstruction of Cu/Au bimetallic alloy where single-atom Cu was embedded on the Au nanoparticle, under electrocatalytic conditions. We identify the migration of isolated Cu atoms from the vertex position of the Au nanoparticle to the stable (100) plane of the Au first atom layer, when the reduction potential is applied. Density functional theory calculations reveal that the surface atom migration would significantly modulate the Au electronic structure, thus serving as the real active site for the catalytic performance. These findings demonstrate the real structural change under electrochemical conditions and provide guidance for the rational design of high-activity bimetallic nanocatalysts.